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No, no execution of skills or Quickslot is allowed by addons. Although if the item in the Quickslot is a companion (or another collection) you can start that via API calls (summon it, unsummon it). But potions, food etc. Alike is nothing that can be used from Quickslot automatically. We can only change the Quickslot wheel to show that particular slot and you manually have to activate it via the normal Quickslot keybind then.
using food from the inventory may work directly though, haven't tested that since years. It was possible in the past, but maybe it's removed meanwhile. but I do not think potions or similar would AND you should Not try that and make ZOs angry because you try to create some automatisms/botting routines... If any API gets revoked/removed because ppl try stuff that should simply not happen, you can be sure the rest of the community here will be very "thankfull"...!
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